Synthesis and characterization of some new Schiff base complexes of group 13 elements, ab initio studies, cytotoxicity and reaction with hydrogen peroxide.
Identifieur interne : 000353 ( Main/Exploration ); précédent : 000352; suivant : 000354Synthesis and characterization of some new Schiff base complexes of group 13 elements, ab initio studies, cytotoxicity and reaction with hydrogen peroxide.
Auteurs : RBID : pubmed:23143208English descriptors
- KwdEn :
- Aluminum (chemistry), Aluminum (pharmacology), Antineoplastic Agents (chemical synthesis), Antineoplastic Agents (chemistry), Antineoplastic Agents (pharmacology), Benzylamines (chemical synthesis), Benzylamines (chemistry), Benzylamines (pharmacology), Cell Line, Tumor, Cell Proliferation (drug effects), Coordination Complexes (chemical synthesis), Coordination Complexes (chemistry), Coordination Complexes (pharmacology), Gallium (chemistry), Gallium (pharmacology), Humans, Hydrogen Peroxide (metabolism), Indium (chemistry), Indium (pharmacology), Models, Molecular, Neoplasms (drug therapy), Schiff Bases (chemical synthesis), Schiff Bases (chemistry), Schiff Bases (pharmacology).
- MESH :
- chemical , chemical synthesis : Antineoplastic Agents, Benzylamines, Coordination Complexes, Schiff Bases.
- chemical , chemistry : Aluminum, Antineoplastic Agents, Benzylamines, Coordination Complexes, Gallium, Indium, Schiff Bases.
- chemical , metabolism : Hydrogen Peroxide.
- chemical , pharmacology : Aluminum, Antineoplastic Agents, Benzylamines, Coordination Complexes, Gallium, Indium, Schiff Bases.
- drug effects : Cell Proliferation.
- drug therapy : Neoplasms.
- Cell Line, Tumor, Humans, Models, Molecular.
Abstract
A novel tetradentate Schiff base, naphthabza-H2=N,N'-bis(naphthylidene)-2-aminobenzylamine, and a series of aluminum(III), gallium(III), and indium(III) complexes with general formula, MLNO3, were synthesized and characterized by elemental analysis, 1H NMR, FT-IR, UV-Vis spectroscopy and thermogravimetric method. The product of the reaction of complexes with hydrogen peroxide was characterized by similar techniques. According to the ab initio calculations aluminum and gallium complexes have five-coordinated structures and indium complex is a six-coordinated one. Also, the growth inhibitory effects of the complexes toward K562 cancer cell line were measured and the results for these complexes are as follows: Al>Ga>In.
DOI: 10.1016/j.saa.2012.09.007
PubMed: 23143208
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The product of the reaction of complexes with hydrogen peroxide was characterized by similar techniques. According to the ab initio calculations aluminum and gallium complexes have five-coordinated structures and indium complex is a six-coordinated one. Also, the growth inhibitory effects of the complexes toward K562 cancer cell line were measured and the results for these complexes are as follows: Al>Ga>In.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="MEDLINE"><PMID Version="1">23143208</PMID><DateCreated><Year>2012</Year><Month>12</Month><Day>03</Day></DateCreated><DateCompleted><Year>2013</Year><Month>05</Month><Day>31</Day></DateCompleted><DateRevised><Year>2013</Year><Month>11</Month><Day>21</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1873-3557</ISSN><JournalIssue CitedMedium="Internet"><Volume>101</Volume><PubDate><Year>2013</Year><Month>Jan</Month><Day>15</Day></PubDate></JournalIssue><Title>Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy</Title><ISOAbbreviation>Spectrochim Acta A Mol Biomol Spectrosc</ISOAbbreviation></Journal><ArticleTitle>Synthesis and characterization of some new Schiff base complexes of group 13 elements, ab initio studies, cytotoxicity and reaction with hydrogen peroxide.</ArticleTitle><Pagination><MedlinePgn>394-9</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1016/j.saa.2012.09.007</ELocationID><ELocationID EIdType="pii" ValidYN="Y">S1386-1425(12)00873-6</ELocationID><Abstract><AbstractText>A novel tetradentate Schiff base, naphthabza-H2=N,N'-bis(naphthylidene)-2-aminobenzylamine, and a series of aluminum(III), gallium(III), and indium(III) complexes with general formula, MLNO3, were synthesized and characterized by elemental analysis, 1H NMR, FT-IR, UV-Vis spectroscopy and thermogravimetric method. The product of the reaction of complexes with hydrogen peroxide was characterized by similar techniques. According to the ab initio calculations aluminum and gallium complexes have five-coordinated structures and indium complex is a six-coordinated one. Also, the growth inhibitory effects of the complexes toward K562 cancer cell line were measured and the results for these complexes are as follows: Al>Ga>In.</AbstractText><CopyrightInformation>Copyright © 2012 Elsevier B.V. All rights reserved.</CopyrightInformation></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Asadi</LastName><ForeName>Mozaffar</ForeName><Initials>M</Initials><Affiliation>Department of Chemistry, College of Science, Shiraz University, Shiraz 71454, Iran. asadi@susc.ac.ir</Affiliation></Author><Author ValidYN="Y"><LastName>Savaripoor</LastName><ForeName>Nooshin</ForeName><Initials>N</Initials></Author><Author ValidYN="Y"><LastName>Asadi</LastName><ForeName>Zahra</ForeName><Initials>Z</Initials></Author><Author ValidYN="Y"><LastName>Ghatee</LastName><ForeName>Mohammad Hadi</ForeName><Initials>MH</Initials></Author><Author ValidYN="Y"><LastName>Moosavi</LastName><ForeName>Fatemeh</ForeName><Initials>F</Initials></Author><Author ValidYN="Y"><LastName>Yousefi</LastName><ForeName>Reza</ForeName><Initials>R</Initials></Author><Author ValidYN="Y"><LastName>Jamshidi</LastName><ForeName>Mehrnaz</ForeName><Initials>M</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType>Journal Article</PublicationType><PublicationType>Research Support, Non-U.S. Gov't</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2012</Year><Month>09</Month><Day>10</Day></ArticleDate></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>Spectrochim Acta A Mol Biomol Spectrosc</MedlineTA><NlmUniqueID>9602533</NlmUniqueID><ISSNLinking>1386-1425</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Antineoplastic Agents</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Benzylamines</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Coordination Complexes</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance>Schiff Bases</NameOfSubstance></Chemical><Chemical><RegistryNumber>045A6V3VFX</RegistryNumber><NameOfSubstance>Indium</NameOfSubstance></Chemical><Chemical><RegistryNumber>BBX060AN9V</RegistryNumber><NameOfSubstance>Hydrogen Peroxide</NameOfSubstance></Chemical><Chemical><RegistryNumber>CH46OC8YV4</RegistryNumber><NameOfSubstance>Gallium</NameOfSubstance></Chemical><Chemical><RegistryNumber>CPD4NFA903</RegistryNumber><NameOfSubstance>Aluminum</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName MajorTopicYN="N">Aluminum</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName><QualifierName MajorTopicYN="N">pharmacology</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Antineoplastic Agents</DescriptorName><QualifierName MajorTopicYN="N">chemical synthesis</QualifierName><QualifierName MajorTopicYN="Y">chemistry</QualifierName><QualifierName MajorTopicYN="N">pharmacology</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Benzylamines</DescriptorName><QualifierName MajorTopicYN="N">chemical synthesis</QualifierName><QualifierName MajorTopicYN="N">chemistry</QualifierName><QualifierName MajorTopicYN="N">pharmacology</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Cell Line, Tumor</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Cell Proliferation</DescriptorName><QualifierName MajorTopicYN="N">drug effects</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Coordination Complexes</DescriptorName><QualifierName MajorTopicYN="N">chemical synthesis</QualifierName><QualifierName MajorTopicYN="Y">chemistry</QualifierName><QualifierName MajorTopicYN="N">pharmacology</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Gallium</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName><QualifierName MajorTopicYN="N">pharmacology</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Humans</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Hydrogen Peroxide</DescriptorName><QualifierName MajorTopicYN="N">metabolism</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Indium</DescriptorName><QualifierName MajorTopicYN="Y">chemistry</QualifierName><QualifierName MajorTopicYN="N">pharmacology</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Models, Molecular</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Neoplasms</DescriptorName><QualifierName MajorTopicYN="N">drug therapy</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N">Schiff Bases</DescriptorName><QualifierName MajorTopicYN="N">chemical 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